Acid-base behaviour of sanguinarine and dihydrosanguinarine

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منابع مشابه

Sanguinarine and Dihydrosanguinarine Accumulation in Argemone mexicana (L) Cell Suspension Cultures Exposed to Yeast Extract 19 Sanguinarine and Dihydrosanguinarine Accumulation in Argemone mexicana (L) Cell Suspension Cultures Exposed to Yeast Extract

Alkaloid contents in Argemone mexicana cell line AMMiF were analyzed during a 36-day culture cycle. The benzophenanthridine sanguinarine (SA) represented the main alkaloid. Dihydrosanguinarine (DHSA), a SA biosynthetic precursor and a less toxic benzophenanthridine, was also identified, based on chromatographic properties and further confirmed by gas chromatography coupled to mass spectrometry....

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Acid and Base Catalyzed Transesterification of Animal Fats to Biodiesel

The present study has been focused on the acid and base transesterification of animal fats (dairy cow and beef) to produce biodiesel by varying process parameters such as catalyst amount, catalyst nature, reaction time and temperature. The maximum biodiesel yield after acid catalysis was 94.1 ± 2.43 and 98.4 ± 2.3 percent for dairy cow and beef t...

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COMPARATIVE STUDIES OF SOLVATOCHROMISM BEHAVIOUR OF COPPER(I1) AND NICKEL(I1) SCHIFF BASE COMPLEXES

A series of Schiff Bases of Ni(II) and Cu(II) using acetylacetone (acac), salicylaldehyde (sal), ethylenediamine (en), and o-phenylendiarnine (dabe) were prepared and characterized. The electronic spectra of some copper chelates in various organic solvents depend strongly on the solvent used and the d-d band of Cu(II) shifts to red with the increase of the Donor Number (DN) of solvent. The ...

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Characterization of a flavoprotein oxidase from opium poppy catalyzing the final steps in sanguinarine and papaverine biosynthesis.

Benzylisoquinoline alkaloids are a diverse class of plant specialized metabolites that includes the analgesic morphine, the antimicrobials sanguinarine and berberine, and the vasodilator papaverine. The two-electron oxidation of dihydrosanguinarine catalyzed by dihydrobenzophenanthridine oxidase (DBOX) is the final step in sanguinarine biosynthesis. The formation of the fully conjugated ring sy...

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ژورنال

عنوان ژورنال: Open Chemistry

سال: 2009

ISSN: 2391-5420

DOI: 10.2478/s11532-009-0079-y